BUCKHORN CLIFFSA preparedness field manual

Compounds and Cleaning · Guide

Phased Purchasing: Which Compounds to Buy First, and in What Order

The book's four-phase plan for building a supply of the 33 compounds: five to start, what each phase unlocks, how much of each to buy, where to buy it, and the free one-page checklist PDF.

FREE PDF4 PHASES33 COMPOUNDS

Quick facts

  • Phase 1, five compounds
    • Baking soda 5 lb
    • non-iodized salt 5 lb
    • calcium hypochlorite 1 lb
    • white vinegar 1 gallon
    • hydrogen peroxide 3% four bottles
  • Phase 2, six: food storage, pests, antimicrobials
    • Activated charcoal 8 oz
    • calcium hydroxide 2 lb
    • borax 4 lb
    • isopropyl alcohol 70% two bottles
    • Epsom salt 4 lb
    • citric acid 2 lb
  • Phase 3, nine: soap, fire, fallout
    • Lugol's iodine 2 oz
    • lye 2 lb
    • diatomaceous earth 4 lb
    • potassium permanganate 8 oz
    • glycerin 16 oz
    • beeswax 1 lb
    • camphor 8 oz
    • petroleum jelly 1 tub
    • washing soda 3½ lb
  • Phase 4, twelve: specialized
    • Sulfur 1 lb
    • potassium nitrate 1 lb
    • sodium nitrate 1 lb
    • boric acid 1 lb
    • castile soap 4 bars
    • cornstarch 2 lb
    • paraffin 5 lb
    • ascorbic acid 1 lb
    • creatine 1 lb
    • electrolytes 4 canisters
    • ethanol 750 mL
    • bentonite clay 2 lb
  • Buy in this order
    • 1 Salt
    • 2 baking soda
    • 3 vinegar
    • 4 calcium hypochlorite
    • 5 peroxide
    • 6 alcohol
    • 7 Epsom salt
    • 8 charcoal
    • specialty compounds last
  • Where to buy
    • Farm supply
    • pool shop
    • pharmacy
    • hardware store
    • grocery
    • online
  • The ruleMaster Phase 1 before moving on. What you know matters more than how much you have

You do not need all 33 compounds at once, and buying them all at once is how people end up with a shelf of chemicals and no idea what to do with any of them. The book builds the supply in four phases, starting with five compounds that cover the most ground, then growing as budget, storage and skill allow. This page is that plan from pages 17 to 19 of the book, with every compound linked to its page on this site and two recipes to make with it, where to buy each one, and the order to buy in.

The quantities are a sensible first buy for one household, not a lifetime supply. Every one of them keeps for years stored right, which is what storing your compounds covers. The sheet at the bottom of the box below is this whole page on one printed page, with checkboxes.

The Phased Purchasing Compound Checklist (PDF), a one page printable PDF

Free download

Get the one-page compound checklist

All four phases on one printed page: every compound with how much to buy and what it is for, checkboxes to tick off, and where to buy each one. Built from the book's phased purchasing plan. Print it and take it to the store.

The PDF comes by email, with my newsletter now and then. Already on the list? You still get it. Read the full page.

The four phases at a glance

Each phase is a shopping trip or two, not a project. Finish one before starting the next, and master Phase 1 before you spend a dollar on Phase 3.

The rule that runs this page: what you know matters more than how much you have. Five compounds you can use beat thirty you cannot.

Phase 1: Your foundation

1

Phase 1 · 5 compounds

Water safety, hygiene, and everyday cleaning

Five compounds that cover the most ground. With these on the shelf you can make drinking water safe, disinfect a kitchen or a wound, clean almost anything, and preserve food. Everything else on this page is built on top of them.

Baking sodaOdor control, cleaning, food prep, first aid
5 lb

The most-used compound in the book: 33 recipes touch it. Buy the big bag.

Non-iodized saltFood preservation, wound care, cleaning
5 lb

Keeps forever, costs almost nothing, and every preserving method runs on it. Non-iodized, no anti-caking agents.

Calcium hypochloriteWater purification; treats thousands of gallons
1 lb

The one pound that replaces a shelf of bleach. Plain pool shock, no algaecide, no clarifier, no stabilizer.

White vinegarMineral removal, odor control, antimicrobial
1 gallon

Nineteen recipes on the site use it. Five percent distilled white; the cleaning strength is for the shop, not the kitchen.

Hydrogen peroxide 3%Surface cleaning, disinfection, antimicrobial
4 bottles

Brown bottles, kept dark. It loses strength once opened, which is why four small bottles beat one big one.

With Phase 1 on the shelf you can

  • Purify water by the barrel
  • Disinfect surfaces and sickrooms
  • Clean a wound and rinse a sore throat
  • Descale, deodorize, scrub, and preserve

Phase 2: Growing your arsenal

2

Phase 2 · 6 compounds

Food storage, pest control, stronger antimicrobial action

Six more, and the shelf starts covering the garden, the pantry, and the first aid kit. Nothing here is exotic; most of it is in a farm store aisle.

Activated charcoalToxin removal, water filtration, air cleaning
8 oz

Food grade, powdered or granular. The binder for a poisoning and the heart of a field water filter.

Calcium hydroxideEgg preservation, pH adjustment, hygiene
2 lb

Hydrated lime, food grade for the eggs. A bag at the farm store; the pickling-lime jar at the grocery is the same thing, smaller.

BoraxPest control, laundry, cleaning, plant care
4 lb

The laundry aisle box. Eight recipes, from the bait that ends an ant problem to flux for soldering.

Isopropyl alcohol 70%Antimicrobial, equipment cleaning, first aid
2 bottles

Seventy percent kills more than ninety-one, because the water keeps it on the surface long enough to work.

Epsom saltPain-relief soaks, plant nutrition, cleaning
4 lb

Magnesium sulfate. The soak after a hard day and the fix for yellowing tomato leaves, from one bag.

Citric acidFood preservation, mineral removal, cleaning
2 lb

Food grade, in the canning aisle or online by the pound. Acid for the canner and the descaler that does not smell like vinegar.

With Phase 2 on the shelf you can

  • Store eggs for months without a fridge
  • Bait ants and roaches, stop mold
  • Filter and clear water, bind a poison
  • Can and preserve with acid

Phase 3: Advanced preparedness

3

Phase 3 · 9 compounds

Soap making, fallout response, pest control, fire starters

Nine compounds that take real skills with them: soap from scratch, a thyroid block, a fire with no match, water with the iron taken out. Buy them as you learn to use them.

Lugol's iodine 2%Fallout protection, wound care, water purification
2 oz

Two ounces goes a long way. The dosing is on its page and in the book; do not guess it.

LyeSoap making, pest control, surface cleaning
2 lb

Sodium hydroxide, 100 percent, no aluminum flakes. The one compound on this page that earns gloves and goggles every time.

Diatomaceous earthPest control, food storage, body care
4 lb

Food grade only; pool-filter DE is a different product and a lung hazard. A dusting in the wheat bucket keeps it clean for years.

Potassium permanganateIron and odor in water, fire starting, wound care
8 oz

Purple crystals that do three unrelated jobs. Stored dry and apart from the glycerin it starts fires with.

GlycerinMedicinal extracts, skin treatment, fire starters
16 oz

Vegetable glycerin, USP. The alcohol-free way to make a tincture for kids, and half of the fire trick above.

Beeswax pelletsFire starters, wound salves, wood preservation
1 lb

Pellets melt evenly and measure by the spoon. A local beekeeper beats the internet on price and smell.

Camphor blocksPain relief, moth repellent, fabric protection
8 oz

The smell of an old tool chest, for a reason: a block in the drawer keeps the rust and the moths off.

Petroleum jellyFire starters, rust prevention, wound protection
1 large tub

Cotton balls and a thumb of jelly: the most reliable fire starter there is, and it never goes bad.

Washing sodaHeavy cleaning, laundry, mineral removal
3.5 lb

Sodium carbonate, baking soda's stronger cousin. Bake baking soda on a sheet pan for an hour and you have made it yourself.

With Phase 3 on the shelf you can

  • Make soap from fat and lye
  • Block the thyroid after fallout
  • Start a fire with no flame
  • Treat iron and odor in well water
  • Keep weevils out of the grain

Phase 4: Specialized capabilities

4

Phase 4 · 12 compounds

Meat curing, fungal treatment, performance, first aid, fire

Twelve compounds for specific jobs. None of them is urgent; each one closes a gap. Pick the ones that match your place: the curing salts if you raise meat, the sulfur if you garden, the creatine and electrolytes if the plan involves hard work.

Sulfur powderPlant and skin fungus, pest control
1 lb

Garden sulfur from the farm store is fine for the dust; the ointment wants a finer, cleaner grade.

Potassium nitrateMeat curing, smoke signals, fire starting
1 lb

Sold as stump remover at the hardware store; read the label for 100 percent potassium nitrate. Stored apart from everything that burns.

Sodium nitrateMeat curing, color preservation, storage
1 lb

The curing salt for long cures. Measured by the gram, never by the handful; the page has the ratios.

Boric acidEye wash, pest control, fungal treatment
1 lb

USP grade if it is going near an eye; the roach powder can be the cheaper one.

Castile bar soapGeneral cleaning, laundry, wound care
4 bars

Pure olive-oil soap, unscented. Four bars grate into gallons of liquid soap, shampoo and wound wash.

CornstarchMoisture control, food thickening, chafe powder
2 lb

Already in the kitchen. Here because it is the base for a chafe powder, a dry shampoo and a sauce from thin soup.

Paraffin waxFire starters, waterproofing, sealing
5 lb

The canning-aisle block. Five pounds is a winter of fire starters and every jar sealed.

Ascorbic acidFood preservation, supplement, antioxidant
1 lb

Vitamin C powder, food grade. A pinch takes the chlorine out of treated water and the brown off cut apples.

Creatine monohydratePhysical endurance, focus, sustained work
1 lb

Five grams a day. The cheapest supplement that does anything, and it keeps for a decade sealed.

Electrolyte supplementHydration, mineral replacement, recovery
4 canisters

Sodium, potassium and magnesium for sweat and hard work; water alone is not enough. I make my own; it is on the food shopping list too.

Ethanol 190 proofMedicinal extracts, antimicrobial, long shelf life
750 mL

Grain alcohol from the liquor store where it is legal to sell; the tincture solvent that is also drinkable, which denatured alcohol never is.

Bentonite clayPoultices, digestive binder, water settling aid
2 lb

Food grade, sodium bentonite. A spoon settles a bucket of muddy water; a paste draws a sting.

With Phase 4 on the shelf you can

  • Cure and smoke meat without a freezer
  • Treat fungus on the skin and in the garden
  • Wash an eye, seal a jar, waterproof a match
  • Keep working hard on bad sleep and little food

The 33rd compound

Honey is the one compound in the book that is not in a phase, because it is food and belongs on the food shopping list. Buy it there, raw and local if you can, and keep a jar with the first aid kit: it dresses a burn, calms a cough and never spoils. Its compound page has the five recipes.

Where to buy each one

Smart buying matters as much as smart storage. Get the right grade from the right place, and the six places below cover all 33. The tag on each card above says which.

Farm supply

Lime, sulfur, diatomaceous earth, Epsom salt, and borax, usually in bulk.

Pool shop

Calcium hypochlorite as pool shock. Check the label: no algaecides, no clarifiers, no stabilizer.

Pharmacy

Hydrogen peroxide, isopropyl alcohol, boric acid, glycerin, and petroleum jelly at pharmaceutical grade.

Hardware store

Lye, washing soda, stump remover, and vinegar, often in larger sizes than the grocery carries.

Grocery

Baking soda, salt, vinegar, borax, cornstarch, paraffin, castile soap: the everyday staples, food grade by default.

Online

The widest selection, but hazmat items (calcium hypochlorite, lye, sulfur) may carry shipping limits or ground-only rules.

Buy in this order

  1. The broadest utility first: salt, baking soda, vinegar, and calcium hypochlorite.
  2. Then the antimicrobials and the garden: hydrogen peroxide, isopropyl alcohol, Epsom salt, and activated charcoal.
  3. Specialty compounds last, as the skill to use each one arrives.
  4. Alongside the compounds, the basic toolkit: a scale, measuring spoons, spray bottles, glass jars, gloves and goggles. Tools and equipment lists every tool and what it is for.

Before you trust it: match the grade to the use

Food grade or USP for anything that goes in a mouth, on a wound or into drinking water. Technical grade is fine for the shop, the drain and the garden. Read the whole label: additives, anti-caking agents, fragrances and stabilizers are what turn a useful compound into the wrong product. The sourcing checklist is the in-store version, and the 33 compounds at a glance table has the grade each one needs.

Master Phase 1 before moving on

Storing what you bought

Everything on this page keeps for years in the same four conditions: cool, dark, dry and sealed, in a container that says what is in it. The exceptions are the ones that want to be apart from each other, and that is a short list worth memorizing.

Oxidizers away from everything that burnsCalcium hypochlorite, potassium permanganate and potassium nitrate on their own shelf, away from the glycerin, the alcohol, the waxes and the petroleum jelly. The never-mix chart checks any pair.
Lye in its own box, with its own glovesSealed, labeled, high, and never in a container that has held anything else. The soap recipe is where it earns its place; the handling page is what to read first.
Peroxide, iodine and alcohol in the darkLight and air weaken them. Small bottles, original containers, replaced on a schedule rather than when they stop working.
Everything labeled the day it comes homeName, grade, date, and the page it is used on. A shelf of white powders in unmarked jars is a hazard, not a supply.

Storing your compounds has the containers and conditions for each one, handling and safety covers gloves, goggles and what to do if something spills, and storage, shelf life and inventory is the inventory sheet.

Where this fits in the rest of the plan

This page is the buying order for the compounds. Around it: the 33 compounds at a glance table is the quick reference with grade and shelf life for each, find a recipe by need goes the other direction, from the problem to the compound, and emergency scenarios says which compounds matter in which crisis. The what-to-stock master list covers everything that is not a compound, and the food shopping list is its one-page partner for the pantry.

Every compound page on this site is free. The recipes with their exact amounts are members' only, and all 138 of them come from the book, which works when the grid does not.

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The most useful thing a membership gives you. Save any page on this site, recipes, charts, and whole field guides included. Arrange them in the order you want, name it, and print one manual with a cover and contents, or keep it as a PDF that opens with no signal.

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Questions this answers

Tap a question for the short answer.

Which chemical compounds should I buy first?

Five: baking soda, non-iodized salt, calcium hypochlorite (plain pool shock), white vinegar and 3 percent hydrogen peroxide. Between them they purify water, disinfect surfaces and wounds, clean nearly anything and preserve food, and most of the recipes on this site start with one of them. Salt, baking soda, vinegar and calcium hypochlorite are the first four to the cart, in that order of breadth.

How much of each compound should I stock?

A sensible first buy, from the book: 5 lb baking soda, 5 lb salt, 1 lb calcium hypochlorite, a gallon of vinegar and four bottles of peroxide for Phase 1; then 8 oz charcoal, 2 lb lime, 4 lb borax, two bottles of alcohol, 4 lb Epsom salt and 2 lb citric acid. Phases 3 and 4 run from 2 oz of Lugol's iodine to 5 lb of paraffin. The full table is on the page and on the one-page PDF.

Where do I buy calcium hypochlorite and lye?

Calcium hypochlorite is pool shock at the pool shop or hardware store; the label must say calcium hypochlorite with no algaecide, clarifier or stabilizer. Lye is sodium hydroxide, sold as drain cleaner at the hardware store; it has to say 100 percent sodium hydroxide, not a blend with aluminum flakes. Both may be ground-shipping only when bought online.

What are the four phases of buying compounds?

Phase 1, the foundation: water safety, hygiene and everyday cleaning, five compounds. Phase 2, growing the arsenal: food storage, pest control and stronger antimicrobials, six more. Phase 3, advanced preparedness: soap, fire, fallout and pest control, nine. Phase 4, specialized: meat curing, fungal treatment, performance and first aid, twelve. Master each before the next.

Do I need all 33 compounds?

No. Most households never need Phase 4, and a shelf of chemicals nobody knows how to use is a hazard, not a supply. Five compounds you can use beat thirty you cannot. Buy the phase that matches your place and your skills, learn it, then decide about the next.

What can I make with the first five compounds?

Drinking water by the barrel, a bleach solution for surfaces and sickrooms, a wound rinse and a sore-throat gargle, an antacid, a descaler for kettles and a rust bath for tools, a surface scrub, and cured meat. Every one of those is a recipe on this site, and four of them are free.

What grade of compound do I need?

Food grade or USP for anything that goes in a mouth, on a wound or into drinking water: salt, baking soda, calcium hydroxide for eggs, boric acid for an eye wash, glycerin, ascorbic acid, bentonite clay. Technical grade is fine for the shop, the drain and the garden. Read the whole label for additives; the sourcing checklist is the in-store version.

Is there a printable compounds shopping list?

Yes. The four phases with every compound, its quantity and its main uses, plus where to buy, on one letter-size page with checkboxes. It is free for subscribers through the form on the page, and members can print it from the page or add it to My Manual.

Keep going

Read nextStoring Your Compounds: Conditions, Containers, Packing and LabelsThe conditions and containers that keep compounds good for years: temperature, light, and humidity targets, which container for which compound, the six packing steps, and what goes on every label.Compounds and Cleaning · Reference

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Compounds and Cleaning · GuideLast reviewed 2026-10-12

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